Event date:
Apr 22 2022 2:30 pm

CCEW-12: New and (More) Direct Routes to Bottom Up Synthesis of Complex Advanced Functional Materials

Speaker(s)
Prof Jawwad A. Darr, University College London
Abstract
Laboratory scale Continuous Hydrothermal Flow Synthesis (CHFS) systems for the controlled synthesis of inorganic nanoparticles (diameter <100 nm) have many potential commercial applications from catalysts to sunscreens and battery materials to fuel cell components. CHFS systems offer many advantages over batch processes: it is a green technology (using supercritical water as the reagent at >374°C and 22.1 MPa), and uses inexpensive precursors (e.g. metal nitrate salts), and parameters such as T, P, etc. can be controlled independently for the synthesis of high-quality, technologically-important functional nanomaterials in a single step (or fewer steps than conventionally used). The Clean Materials Technology Group at UCL, now use CHFS made intimately mixed metal oxide precipitates as precursors to the direct synthesis of “difficult to make” solid-state phases using only a single heat treatment step and no grinding (i.e., “Bake Without the Shake!”). This approach can be used for rapid materials discovery and also to manufacture materials using continuous, low energy manufacturing methods which are inherently scalable. As well as the use of CHFS for battery materials discovery, the talk will discuss the design and operation of a scaled-up CHFS Pilot Plant capable of Kg/h synthesis of nanoceramics as well as future directions for the CHFS technology. A review article on the topic has been published and gives an excellent overview on the technology, see Darr JA, et al. “Continuous Hydrothermal Synthesis of Inorganic Nanoparticles: Applications and Future Directions”, ACS Chem. Rev. 2017, 117 (17), 11125–11238

Jawwad Darr is Professor of Materials Chemistry at University College London.  He has published over 200 academic publications in advanced functional materials including catalysts and batteries (h-index 50, 9k citations, google scholar), has three patents and has graduated over 45 PhD students (as of 2021).  From 2016 to 2021, he was Vice Dean of Enterprise in the Maths and Physical Sciences faculty at UCL in, which he was supporting UCL’s faculty engagement with industry. He has strong research collaborations with industry and is a regular speaker at industrial forums and academic events in a wide range of topics.  As well as his own latest research, he teaches on topics related to green chemistry, applications of advanced functional materials (including batteries) and at outreach lectures in the UK and overseas. 

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In 2017, he co-founded the UPSIGN charity (UK-Pakistan Science and Innovation Global Network; www.upsign.org.uk) that works to support, educate and connect British Pakistani and Pakistani academics.  In his UPSIGN work, he is involved in public outreach workshops and lectures, training Pakistani academics and students, and developing training and workshops to support underprivileged undergraduate black and minority Asian students in research. In his spare time, he enjoys dabbling in interior design, reading about the origins of life and evolution, watching/playing association football.